Posts Tagged ‘SWAP’

EPA submits Greenhouse Gas rules to White House

Friday, April 23rd, 2010

It will be interesting to watch how the recently submitted EPA rules to the White House drive new dialogue among business leaders on how reporting requirements will affect bottom lines.  How will the new “tailoring rules” ultimately apply?

The Wall Street Journal reports: “EPA officials say the agency wants to finalize the rule by the end of April, but that timetable may slip into May. The EPA said earlier this year that the first phase would likely target facilities that emit more than 75,000 to 100,000 tons of carbon-dioxide equivalent a year starting in 2011. The agency hasn’t yet made clear the exact first-phase threshold.”

Landfills may be particularly impacted and would present a valuable opportunity  for municipal leaders to explore how the SWAP could be implemented to safely and cheaply process landfill gas (LFG) for power.  A recent article from the New York Times delves into the broad potential impact of these rules.

In the United States alone, there were more than 3,500 landfills in operation as documented by the EPA in 1995.  In 2003, we generated 236.2 million tons of municipal solid waste (MSW), an increase of 15 percent above 1990 levels and 168 percent above 1980 levels.  The number of landfill gas projects that generate electricity on-site, supply industrial gas-fired boilers, or produce substitute natural gas rules, such as compressed natural gas (CNG) jumped from approximately 400 in 2005 to 519 in 2009.

Many landfills are now accepting large quantities of construction and demolition debris in addition to MSW, which in sufficient quantities results in landfill gases with relatively high concentrations of hydrogen sulfide (H2S).  H2S is generally the byproduct of bacterial decomposition of construction wastes, particularly drywall containing calcium sulfate.   There is an interesting article from Environmental Leader on H2S and potential reporting requirements this month.

Landfill gas cleanup is likely to experience significant growth in the future as a renewable energy option.  Each landfill is normally a stand-alone operation close to an urban location.  Integrating SWAP technology at these locations, it is believed, would require minimal interface activities with existing processes.

www.swapsol.com

Swapsol supports Worldwatch natural gas play at Copenhagen

Wednesday, December 2nd, 2009

Could natural gas be a player in the new world climate order?  It looks like three organizations will be pushing for just that in Copenhagen next week.   The American Clean Skies Foundation (ACSF), the UN Foundation and the Worldwatch Institute say they will jointly “explore the potential for natural gas to accelerate the world’s transition to a low-carbon economy,” according to Worldwatch.

Sour gas pipeline, courtesy CBC.CA

Sour gas pipeline, courtesy CBC.CA

They will announce that new sources of unconventional gas could (and would) more quickly help the world turn away from oil and coal as a primary source of energy and spur new energy policy.  That’s correct if certain truths are taken into account.  There are considerable reserves of natural gas that remain capped due to high concentrations of hydrogen sulfide (H2S) that make them “sour.”  Many of these reserves are in remote areas where the cost of production makes it economically unattractive.  In fact, nearly 40 percent of the world’s natural gas reserves is sour, according to French oil and gas giant Total, s.a.

Many experts say more attention needs to be paid to renewable sources like wind and solar.  That’s true, but where are we now?  Wind and solar are growing sources of energy, but they currently aren’t developed enough to make an overnight change.  Will natural gas be the answer?

H2S, sometimes known as “sewer gas,” is the oil and gas industry’s enemy No. 1.  A chief part of the refining process is removing sulfur and H2S from raw streams to be able to bring refined natural gas to market. So yes, natural gas should play a fundamental role in any low-carbon policy proposed.  But this is possible only if more attention is paid to technological advances in refining it.

As we look toward Copenhagen, SWAPSOL agrees with the Worldwatch Institute that greater investment is needed in natural gas to play a pivotal role in a low-carbon environment.  Wind and solar technologies are exciting and are quickly gaining ground in the fight against climate change, but today we have an opportunity to both lower carbon emissions using natural gas, as well. Incorporating natural gas into the mix of solutions will also create needed jobs through additional investment in refining technologies. These technologies hold the key to preventing H2S from holding a tremendous volume of natural gas hostage.

With the SWAP, we can eliminate two “bad actors” in a single chemical process, protect the environment and improve bottom lines by reducing costs and creating jobs simultaneously.  We can look at CO2 not as an enemy, but as a friend and use it to profit in a new energy economy.

DISCOVERY TO REDUCE HUMAN IMPACT ON GLOBAL WARMING

Monday, October 26th, 2009

CO2 conversion eliminates industry liability opens door to new energy economy

HOUSTON (Oct. 28, 2009) – Two New Jersey scientists have discovered a simple chemical process to break down carbon dioxide (CO2) and eliminate nuisance pollutants, such as hydrogen sulfide (H2S) in refining operations. Their discovery could redefine how science looks at energy. SWAPSOL Corp. will present to industry on Oct. 28, “Carbon Focus Day,” at the Global Refining Strategies Summit in Houston.

The invention changes preconceived notions about energy and chemistry. Raymond Stenger, environmental engineer, and James Wasas, an entrepreneurial chemist, developed the Stenger-Wasas Process (SWAP) based on a previously unknown exothermic interaction between H2S and CO2 that eliminates both. The SWAP is independently verified by standard analytical instruments to convert CO2 by more than 99 percent into carbon-sulfur polymers (Carsuls), water and sulfur in the presence of H2S over an abundant and inexpensive catalyst. The SWAP can also recycle waste hydrocarbons (compounds containing carbon and hydrogen) and break down CO2 in a self-sustaining cycle.

“We are building our company around the chemistry,” said Wolf Koch, Ph.D., Director of SWAPSOL Corp. “We are now detailing processes under which we will review potential business relationships with interested parties with intent to launch initial steps next year.”

Thermodynamic and chemical kinetics studies indicate that the SWAP is exothermic, and the heat liberated can be managed and controlled. Independently conducted gas chromatography studies (GC) verified H2S reduction to below 4 ppb.

Eliminating carbon liabilities for industry

By eliminating greenhouse gases, refiners and other carbon-emitters may profit by not polluting and by avoiding carbon penalties. Wasas, SWAPSOL’s chief science officer, predicts the SWAP could also earn carbon credits for those who implement the technology.

Hydrogen sulfide is the oil and gas industry’s enemy No. 1,” Wasas said. “Tremendous money and energy is required to get rid of H2S, and traditional methods create more hazardous waste, increasing costs and further polluting the environment.”

Hydrogen production, landfill waste potential

The SWAP can be used to purify gas inside landfills prior to combustion, thereby eliminating the harmful release of pollutants into the air. The SWAP-driven sulfur cycle also allows for related reactions that can produce hydrogen from hydrogen sulfide. For refiners this may be a cost-effective solution to recover hydrogen while it may find other applications for fuel cells.

“I can’t tell you how proud we are of the work Jim and I have been able to accomplish,” said Stenger, SWAPSOL’s president. “To be able to make a contribution like this to the world is something I’ve dreamed about for years.”

National Chemistry Week Seminar : Can a chemical reaction help fight global warming?

Tuesday, September 1st, 2009

Wednesday, October 21, 2009

Could a Sour Natural Gas Process Convert Carbon Dioxide (CO2) and Hydrogen Sulfide (H2S) into harmless compounds?

Attend discussion on if an exothermic chemical reaction could contribute in the fight against global warming and climate change.

WHAT:

The Stenger Wasas Process (SWAP): A suite of hydrocarbon refining solutions that, in the laboratory, has been verified to rapidly reduce H2S to below detectable limits by gas chromatography (under 4ppb) and may be able to convert CO2 into carbon, water and sulfur industrially.  Discoverers of the SWAP invite academicians and experts to discuss the science and its potential contributions to the global warming solution.

WHERE:

Philip Alampi Auditorium, Rutgers University Cook Campus
School of Environmental and Biological Sciences
71 Dudley Road (corner of College Farm and Dudley Rd.)
New Brunswick, NJ

WHEN: Wed., Oct. 21

2:30 p.m. – 4:30 p.m.

RSVP:             www.swapsol.com/events.php

Open Admission      Q & A Following

WHO:

Raymond Stenger and James Wasas invite members of the academic and professional communities on Wednesday, Oct. 21, 2009, to learn about the Stenger-Wasas Process (SWAP), proposing that a reaction between carbon dioxide (CO2) and hydrogen sulfide (H2S) eliminates both (2H2S + CO2 => 2H2O + 2S + C) in a mildly exothermic reaction and could alter the course of global warming and impact escalating energy costs.  Hear and discuss the science behind the SWAP and its potential impact on the hydrocarbon industry.

PARTICIPANTS

  • Raymond Stenger (B.S.,WV University ‘57)
  • James Wasas (B.S., Rutgers ‘68)
  • Wolf Koch, Ph.D, Chemical Engineering, University of Cincinnati (B.S., Rutgers ‘68), President, Technology Resources International, Inc.
  • Gene Hall, Ph.D, Analytical Chemistry, Rutgers University (independent GC verification)
  • Roy Drayton, Ph.D, President, Thermal Hazard Solutions, Inc.  (independent thermodynamics and chemical kinetics verification)
  • Randa Fahmy-Hudome, Former U.S. Associate Deputy Energy Secretary

Stenger and Wasas will discuss the catalytic and recombinant science behind the reaction.  Dr. Wolf Koch will discuss the potential commercial applications.  Q & A will follow: Dr. Hall will answer questions about his independent chemical and gas chromatography (GC) analysis; Dr. Drayton will answer questions about his findings and verifications of thermodynamic and chemical kinetic results showing scalability of the SWAP.

If you would like to attend, please visit: www.swapsol.com/events.php

Can sulfur recovery breakthroughs reduce our environmental footprint?

Saturday, August 22nd, 2009

There has been a recent discovery of a previously unknown exothermic reaction between CO2 and H2S.  It’s a reaction that may fundamentally alter the hydrocarbon industry.  Work continues.  It’s called the Stenger-Wasas Process (SWAP) developed by Ray Stenger and Jim Wasas.  And it may make obsolete traditional petroleum methods, such as the Claus Process and its variants.

The SWAP: Unrefined sour natural gas is fed into the catalytic reactor, where the SWAP reaction occurs between CO2 and H2S. Refined gas flows past the separator. CO2 and H2S are converted into water, sulfur and carbon in the collector. In a reaction that can start in less than one second at very moderate temperatures, the result of the SWAP is refined natural gas.

Brief Overview

Sulfur contaminants such as hydrogen sulfide (H2S), carbonyl sulfide (COS), and mercaptans in gas streams can create unacceptable levels of sulfur emissions in power applications or poison catalysts used in chemical synthesis. Sulfur contaminants are usually reduced to less than 300 ppm for power generation and considerably lower (<1 ppm) for the synthesis of methanol, ammonia, and Fischer-Tropsch (FT) liquids.

Sulfur recovery unit (courtesty: C&I)

Sulfur recovery unit (courtesy: C&I)

Sulfur Recovery Processes

Removing sulfur from a natural gas or syngas process stream is only part of the story. The residual sulfur present in an acid gas stream must then be recovered to prevent environmental and safety harms, as well as meet operator permit requirements. Two main technologies have traditionally been used commercially to recover sulfur: the Claus process (partial combustion) for high levels of sulfur, and catalytic Redox processes, for relatively low levels of sulfur. In recent years, bio-chemical based technology, the Thiopaq Process, has been developed and commercially implemented. Other recent developments include the development of hybrid processes that combine Claus and Redox technology and are used for tailgas cleanup in Claus plants.

The SWAP has been verified by gas chromatography in the laboratory to reduce H2S to below the limit of detection (about 4ppb) in a single pass through the SWAP column.

The SWAP in the laboratory

The SWAP in the laboratory

Classified as hazardous waste by the EPA, H2S disposal requires expensive processing, i.e. the Claus Process. The SWAP may reduce related capital costs for the H2S disposal resulting from crude oil desulfurization, while simultaneously eliminating substantial amounts of CO2.

CLAUS PROCESS

Technology Description

In the Claus process, a high H2S concentration stream is the feedstock for recovery to elemental sulfur. Roughly 1/3 of the H2S is burnt (partial combustion) to form sulfur dioxide (SO2). The remaining H2S reacts with the synthesized SO2 over an alumina or bauxite catalyst to produce elemental sulfur. Depending on their concentrations, the unreacted components (tail gas), such as residual SO2, CO2, and H2S, are either emitted, thermally oxidized, or further treated in an additional recovery process.

(US Environmental Protection Agency, AP42, 5th Edition, “Compilation of AirPollutant Emissions Factors Volume 1: Stationary Point and Area Sources, 1995) The Claus process is thermodynamically limited to ~97 percent sulfur recovery, although additional treatment steps, such as tail gas sulfur recovery, can increase the recovery rate.

Commercial Manufacturers and Applications

The Claus process is the oldest commercial sulfur treatment process, with development dating back to the late 19th century. Today, Claus processes are the main step used for elemental sulfur production worldwide-in fact, 90 percent to 95 percent of the sulfur recovered in the United States was from the Claus process. Almost 40 companies operate over 1000 Claus processes in the United States, recovering nearly 9 million tons per year of sulfur. The petroleum and natural gas industries are the main users of the technology, with IGCC applications making up a small but growing segment of the user population.

With catalytic refining, environmental footprint and operational costs can be lowered. This and other breakthroughs may change the landscape of hydrocarbon refining.  www.swapsol.com